You said ->"The molecular structure of nitrogen is several times larger than that of air used in conventional inflation systems."
This is BS. "air used in conventional inflation systems" is already 80% nitrogen. Most of the rest is oxygen which has a similar molecular size. I've seen it claimed that Nitrogen migrates through rubber at a much lower rate than oxygen (1/3 the rate????). However, I don't think miagration through the rubber is a major problem for either. Most air, or nitrogen leaks out through the valve or past the bead, not through the rubber.
You said -> "Another benefeit of nitrogen is that it has far less water content than standard air, meaning nitrogen is inert and will not cause long term corrosion or pitting of the inside of your wheel or tires."
It is not the water that corrodes your tires, it is the oxygen. The water does act like a catalyst, but the amount of water in "air" is trivial in a typical tire as far as promoting corrosion is concerned. Be honest now, when was the last time you had a problem with pitting on the inside of a wheel? For me it is never.
You said -> "Another benefeit of nitrogen...it is stable at high temperatures; it does not expand when heated or contract when cooled, this results in a CONSTANT air pressure inside your tires, whether they are hot from driving or cold from sitting. Regular air expands as you drive creating more pressure in your tires, reducing as your car sits and the tires cool."
This is total BS. First of all air is 80% Nitrogen. But more importantly, dry air and pure nitrogen have almost exactly the same pressure vs. temperature relationship at typical automotive tire pressures. If you have a lot of moisture in the air, it can afffect the relationship somewhat, but not enough that you would notice. Most commerical compressors do a fair job of removing moisture from air, so the difference between shop air and nitrogen is trivial for typical automobiles and light trucks.
Racers use nitrogen to avoid having moisture in the tires. Becasue of the high speeds and high cornering loads, the tires on race cars get very hot. Optimum handling depends on minute changes in air pressure. The pressure increases as the tire heats up. The pressure build-up as the tire heats up is slightly more predcitible with pure nitrogen than with "local" air becasue the moisture content of "local" air can vary depending on the conditions when the tires were filled. We are talking about tiny differences (not even 1/2 lb of pressure). There is no chance the typical driver is going to know the difference.
The only advantage I am willing to conceede is that pure nitrogen will help preserve the inside of the tire carcass longer than normal air. The O2 in air will react with the carcass and degrade it over time. However, "over time" is 10 years or more. For most of us, this is not going to matter at all. For large fleets that recap tires, it might matter, escpecially if they maintain their own nitrogen system. However, if you are paying someone to fill your tires with Nitrogen, I think you are making a terrible economic decision.
Now for the killer point - most tire stores that inflate tires with "nitrogen" aren't using pure bottled nitrogen, they are using a commercial nitrogen generator. These don't actually provide "pure" nitrogen. They remove O2 and water vapor from the air and provide something close to 95% nitrogen (when properly maintained). So you are paying to go from around 80% nitrogen to 95% nitrogen. Plus - when the tire is mounted, it's volume is filled with plain old air. This mean's that about 25% of the gas in the tire after it is inflated to pressure is the plain old air that was in the tire when it was first mounted. So after the tire is finally filled to its working pressure, approximately
20% of 25% of the air that was in the tire after mounting (but before pressurization) is oxygen plus another 5% of 75% of "nitrogen" added to pressurize the tire - so 5% to 10% of the gas in the tire is still oxygen. So in the end, you are paying to go from a gas containing 20% oxygen to one conating around 8% oxygen. I can't imagine this is worthwhile - except to the people selling the service. Plaus what ahppens when you add air to the tire to compensate for leaking, or temperature changes? After a couple of years, what do you suppose the composition of the air in the tire will be?
I don't suppose this can be called an obvious scam, but you should check out the source of most of the "positive" talk about nitrogen for automotive tires. Mostly it comes from stores selling nitorgen for tires, companies than manufacturer the nitrogen generators, and tire stores providing nitrogen filling as a gimmick to attarct customers.
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Ed