Well you have supplied information about the switch and about your competence so that is what gets commented on - The rest is a guessing game
Not all injectors work the same You aren't going to come up with a universal device for Pre-OBDII cars that converts the injector signal into miles per gallon
However as a general proposition the duration of the pulse will correlate to fuel consumption so you should be able to tell if consumption increases or decreases. But not very accurately by how much.
I believe if you start with a ordinary car that gets 57 mpg, you can rig it with a switch so that when you flip the switch you get 34 mpg
but no I don't believe you can improve mileage that much with something that can be controlled by a switch. Increasing efficiency that much would have to involve a redesign of the engine and perhaps even the drive train.
Does "non-invasively" means not disconnecting anything or taking anything apart?
Measuring how much fuel is used for a specific repeatable drive cycle seems like the simplest way to get what you say you want.