In a properly equipped shop (like ours), we hook up the car to an AC "recovery" machine, that creates a strong vacuum (~30") to remove all air, moisture, old refrigerant, and oil from the system. If the system holds that vacuum for around
30 minutes, we assume there are no leaks, and recharge the system with the proper amount of oil and refrigerant. We then monitor the pressure to make sure there are still no leaks, and that the high- and low-side pressures are within spec with the compressor running. It's quite possible for an internal relief valve to stick, causing the pressure to spike to dangerous levels, or for the compressor to be faulty, and not produce the correct pressures in use.