Let's forget all the little biy squabling and answer the OP's question.
The voltage MUST be checked across the battery posts - pos to neg. If the voltage is within spec (under 14.6 with a fully charged battery) and the battery still boils, the battery is shot.
Checking from pos to engine or body ground will GENERALLY give a higher voltage if the ground is bad. If the wire from the alternator output has high resistance, measuring from the alt output t0 ground will give a higher reading than across the battery.