The stock alternator is decent compared to the alternators on the pre-'96 cars. You shouldn't have any charging or cooling problems as long as those systems aren't already degraded. On another note...you won't notice a difference with the pullies. Your butt cannot discern a 5 rwhp difference. Shoot...you can barely see it on a track over a quarter mile (~0.5 mph increase). If you need to spend that much money for something, you'd be better off with the timing adjuster. That one makes torque you can feel.
No problem.