That rust (on the walls of the hat) isn't why the OP is pounding on his rotors with a sledge.
It isn't clear if the rust in your picture came from the rotors or arrived from the pads. Picture 5 indicates that most of the rust came from the rotor itself not the pads. But let's say for the sake of the argument it wouldn't be there if ceramic pads were used.
The difference between rust that forms in the space between hub and rotor and the rust that arrives from somewhere else is that the rust that forms in place expands. And since it has no place to go it is very tightly compacted and builds enormous pressure. That is reason it is as if the rotors are welded on. Any place that is a tight fit to begin with will need very little rusting to build huge amount of force.
Once that bond in the rotor to hub contact areas breaks free, then the rest of the rust shown in your picture is much more crumbly and soft and doesn't have anywhere near the same holding power as rust that formed in a confined space.
Bottom line, the type of pads used on the vehicle has nothing to do with the OP pounding on the rotors with a sledge hammer to break them free. The hammer is used to brake the bond. To get it past the crumbly dust is just a matter of wiggling it so that it crushes the loose rust as it is removed.
-jim