Hmmm, if you acquired the car with 40K or 50K miles, you have only the original owner's word that the Syntec was used from day one and that the oil was changed according to Ford's recommended intervals. I think a more likely cause of the buildup is neglected oil changes, whether using conventional or synthetic oil, and the original owner switched to Syntec in hopes of cleaning out the sludge. As far as the sludge in the valve cover, it was probably there before you acquired the vehicle, but it is theoretically possible (though not probable) that the sludge came from the Royal Purple or Amsoil products or some kind or reaction from switching products.